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O acoplamento dipolar residual (residual d … O acoplamento dipolar residual (residual dipolar coupling (RDC), em inglês) entre dois spins numa molécula ocorre se as moléculas em solução exibem un alinhamento parcial que conduz a uma média incompleta dos anisótropos espaciais. O alinhamento molecular parcial conduz a uma média incompleta das interacções magnéticas anisótropas tais como a interacção magnética dipolo-dipolo (também chamada acoplamento dipolar), o deslocamento químico anisótropo, ou a interacção eléctrica de quadripolos. As interacções magnéticas anisótropas residuais estão a tornar-se cada vez mais importantes em espectroscopia RMN biomolecular.tantes em espectroscopia RMN biomolecular.
, El acoplamiento dipolar residual (Residual … El acoplamiento dipolar residual (Residual Dipolar Coupling (RDC) por su nombre en inglés)entre dos spines en una molécula ocurre si las moléculas en solución exhiben un alineamiento parcial que conduce a un promediado incompleto de los anisótropos espaciales. El alineamiento molecular parcial conduce a un promediado incompleto de las interacciones magnéticas anisótropas tales como la (también llamada acoplamiento dipolar), el desplazamiento químico anisótropo, o la interacción eléctrica de cuadripolos. Las interacciones magnéticas anisótropas residuales están cobrando relevancia en espectroscopia RMN biomolecular.ancia en espectroscopia RMN biomolecular.
, The residual dipolar coupling between two … The residual dipolar coupling between two spins in a molecule occurs if the molecules in solution exhibit a partial alignment leading to an incomplete averaging of spatially anisotropic dipolar couplings. Partial molecular alignment leads to an incomplete averaging of anisotropic magnetic interactions such as the magnetic dipole-dipole interaction (also called dipolar coupling), the chemical shift anisotropy, or the electric quadrupole interaction. The resulting so-called residual anisotropic magnetic interactions are becoming increasingly important in biomolecular NMR spectroscopy.mportant in biomolecular NMR spectroscopy.
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The residual dipolar coupling between two … The residual dipolar coupling between two spins in a molecule occurs if the molecules in solution exhibit a partial alignment leading to an incomplete averaging of spatially anisotropic dipolar couplings. Partial molecular alignment leads to an incomplete averaging of anisotropic magnetic interactions such as the magnetic dipole-dipole interaction (also called dipolar coupling), the chemical shift anisotropy, or the electric quadrupole interaction. The resulting so-called residual anisotropic magnetic interactions are becoming increasingly important in biomolecular NMR spectroscopy.mportant in biomolecular NMR spectroscopy.
, El acoplamiento dipolar residual (Residual … El acoplamiento dipolar residual (Residual Dipolar Coupling (RDC) por su nombre en inglés)entre dos spines en una molécula ocurre si las moléculas en solución exhiben un alineamiento parcial que conduce a un promediado incompleto de los anisótropos espaciales. incompleto de los anisótropos espaciales.
, O acoplamento dipolar residual (residual dipolar coupling (RDC), em inglês) entre dois spins numa molécula ocorre se as moléculas em solução exibem un alinhamento parcial que conduz a uma média incompleta dos anisótropos espaciais.
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Residual dipolar coupling
, Acoplamiento dipolar residual
, Acoplamento dipolar residual
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