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Triphenylphosphine phenylimide is the orga … Triphenylphosphine phenylimide is the organophosphorus compound with the formula Ph3P=NPh (Ph = C6H5). It is a white solid that is soluble in organic solvents. The compound is a prototype of a large class of Staudinger reagents, resulting from the Staudinger reaction. The phosphine imides were first prepared in the laboratory of Nobelist Hermann Staudinger. His synthesis involved the direct reaction of triphenylphosphine with phenylazide. Ph3P + N3Ph → Ph3P=NPh + N2 X-ray crystallography establishes that the P-N-C angle is bent (130.4°) and the P-N distance is 160 pm.t (130.4°) and the P-N distance is 160 pm.
, 苯亚氨基三苯基磷是一种有机磷化合物,化学式为Ph3P=NPh,其中Ph = C6H5。它是白色固体,可溶于有机溶剂。它可在施陶丁格反应中生成。 这种亚氨基磷最初于赫尔曼·施陶丁格的实验室中合成,他通过三苯基膦和叠氮苯的反应制得。 Ph3P + N3Ph → Ph3P=NPh + N2 X射线衍射表明分子中P-N-C的键角为130.4°,P-N键长为160 pm。
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Tetraphenylphosphanimine
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rdfs:comment |
Triphenylphosphine phenylimide is the orga … Triphenylphosphine phenylimide is the organophosphorus compound with the formula Ph3P=NPh (Ph = C6H5). It is a white solid that is soluble in organic solvents. The compound is a prototype of a large class of Staudinger reagents, resulting from the Staudinger reaction. The phosphine imides were first prepared in the laboratory of Nobelist Hermann Staudinger. His synthesis involved the direct reaction of triphenylphosphine with phenylazide. Ph3P + N3Ph → Ph3P=NPh + N2 X-ray crystallography establishes that the P-N-C angle is bent (130.4°) and the P-N distance is 160 pm.t (130.4°) and the P-N distance is 160 pm.
, 苯亚氨基三苯基磷是一种有机磷化合物,化学式为Ph3P=NPh,其中Ph = C6H5。它是白色固体,可溶于有机溶剂。它可在施陶丁格反应中生成。 这种亚氨基磷最初于赫尔曼·施陶丁格的实验室中合成,他通过三苯基膦和叠氮苯的反应制得。 Ph3P + N3Ph → Ph3P=NPh + N2 X射线衍射表明分子中P-N-C的键角为130.4°,P-N键长为160 pm。
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rdfs:label |
Triphenylphosphine phenylimide
, 苯亚氨基三苯基磷
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