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In organic chemistry, thioenols (also know … In organic chemistry, thioenols (also known as alkenethiols) are alkenes with a thiol group (−SH) affixed to one of the carbon atoms composing the double bond (i.e. C=C−SH). They are the sulfur analogs of enols (hence the thio- prefix). Alkenes with a thiol group on both atoms of the double bond are called enedithiols. Deprotonated anions of thioenols are called thioenolates. These structures exhibit tautomerism to give thioketones or thioaldehydes, analogous to keto–enol tautomerism of carbonyl structures.o–enol tautomerism of carbonyl structures.
, I tioenoli (o entioli, o ancora alchenetio … I tioenoli (o entioli, o ancora alchenetioli) sono composti organici affini agli enoli, caratterizzati dalla presenza di un doppio legame C=C e di un gruppo tiolico -SH direttamente legato ad uno dei due atomi di carbonio interessati nel doppio legame. La formula condensata generica è HS-CR=CR'R'', dove R, R' e R'' rappresentano sostituenti organici di natura idrocarbutica.tituenti organici di natura idrocarbutica.
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| rdfs:comment |
In organic chemistry, thioenols (also know … In organic chemistry, thioenols (also known as alkenethiols) are alkenes with a thiol group (−SH) affixed to one of the carbon atoms composing the double bond (i.e. C=C−SH). They are the sulfur analogs of enols (hence the thio- prefix). Alkenes with a thiol group on both atoms of the double bond are called enedithiols. Deprotonated anions of thioenols are called thioenolates. These structures exhibit tautomerism to give thioketones or thioaldehydes, analogous to keto–enol tautomerism of carbonyl structures.o–enol tautomerism of carbonyl structures.
, I tioenoli (o entioli, o ancora alchenetio … I tioenoli (o entioli, o ancora alchenetioli) sono composti organici affini agli enoli, caratterizzati dalla presenza di un doppio legame C=C e di un gruppo tiolico -SH direttamente legato ad uno dei due atomi di carbonio interessati nel doppio legame. La formula condensata generica è HS-CR=CR'R'', dove R, R' e R'' rappresentano sostituenti organici di natura idrocarbutica.tituenti organici di natura idrocarbutica.
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Tioenoli
, Thioenol
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