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|
TRISPHAT (full name tris(tetrachlorocatech … TRISPHAT (full name tris(tetrachlorocatecholato)phosphate(1−)) is an inorganic anion with the formula P(O2C6Cl4)−3 often prepared as the tributylammonium ((C4H9)3NH+) or tetrabutylammonium ((C4H9)4N+ salt. The anion features phosphorus(V) bonded to three tetrachlorocatecholate (C6Cl4O2−2) ligands. This anion can be resolved into the axially chiral enantiomers, which are optically stable (the picture shows the Δ enantiomer). The TRISPHAT anion has been used as a chiral shift reagent for cations. It improves the resolution of 1H NMR spectra by forming diastereomeric ion pairs.ectra by forming diastereomeric ion pairs.
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| http://dbpedia.org/ontology/alternativeName
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Tetrabutylammonium tris(tetrachlorocatecholato)phosphorus(1−)
, Bu4N+ PHAT−
, 1-Butanaminium, N,N,N-tributyl-, (OC-6-11-Δ)-tris[3,4,5,6-tetrachloro-1,2-benzenediolato(2-)-κO1,κO2]phosphate(1−) (1:1)
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| http://dbpedia.org/ontology/iupacName
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Tetrabutylammonium tris(3,4,5,6-tetrachlorobenzene-1,2-diolato-κ2O1,O2)phosphorus(V)
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14863422
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4204
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1095946881
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, http://dbpedia.org/resource/Phosphorus_pentachloride +
, http://dbpedia.org/resource/Diastereomeric +
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Trisphat.png
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Delta-TRISPHAT-3D-balls.png
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170
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170
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Tetrabutylammonium trisphosphorus
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| http://dbpedia.org/property/othernames
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1
, Tetrabutylammonium trisphosphorus
, Bu4N+ PHAT−
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424874343
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| rdfs:comment |
TRISPHAT (full name tris(tetrachlorocatech … TRISPHAT (full name tris(tetrachlorocatecholato)phosphate(1−)) is an inorganic anion with the formula P(O2C6Cl4)−3 often prepared as the tributylammonium ((C4H9)3NH+) or tetrabutylammonium ((C4H9)4N+ salt. The anion features phosphorus(V) bonded to three tetrachlorocatecholate (C6Cl4O2−2) ligands. This anion can be resolved into the axially chiral enantiomers, which are optically stable (the picture shows the Δ enantiomer). The TRISPHAT anion has been used as a chiral shift reagent for cations. It improves the resolution of 1H NMR spectra by forming diastereomeric ion pairs.ectra by forming diastereomeric ion pairs.
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| rdfs:label |
TRISPHAT
|
