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Self-healing hydrogels are a specialized t … Self-healing hydrogels are a specialized type of polymer hydrogel. A hydrogel is a macromolecular polymer gel constructed of a network of crosslinked polymer chains. Hydrogels are synthesized from hydrophilic monomers by either chain or step growth, along with a functional crosslinker to promote network formation. A net-like structure along with void imperfections enhance the hydrogel's ability to absorb large amounts of water via hydrogen bonding. As a result, hydrogels, self-healing alike, develop characteristic firm yet elastic mechanical properties. Self-healing refers to the spontaneous formation of new bonds when old bonds are broken within a material. The structure of the hydrogel along with electrostatic attraction forces drive new bond formation through reconstructive covalent dangling side chain or non-covalent hydrogen bonding. These flesh-like properties have motivated the research and development of self-healing hydrogels in fields such as reconstructive tissue engineering as scaffolding, as well as use in passive and preventive applications.se in passive and preventive applications.
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* GPC
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* DSC
* NMR
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* DMA
* Rheology
** Rheometry
** Viscometry
, ; Chain-growth polymerisation
: Free radical polymerization
: Controlled radical polymerization
:: ATRP
:: RAFT
:: Nitroxide mediated radical polymerization
; Step-growth polymerization
:Condensation polymerization
: Addition polymerization
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:: Polypropylene
:: Polyisobutylene
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: Polyester
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: Vinyl polymers
:: PVC
:: PVA
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; Structure
: Homopolymer
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:: Hydrogels
::: Self-healing hydrogelsls
:: Hydrogels
::: Self-healing hydrogels
, * Flory
* Heeger
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* Shirakawa
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* de Gennes
* Ziegler
* Staudinger
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* Baekeland
* Hayward
* Braconnot
, * Architecture
* Tacticity
* Morphology
* Degradation
* Phase behavior
** Mark–Houwink theory
** UCST
** LCST
** Flory–Huggins solution theory
** Coil-globule transition
, ; Industrial production
: Extrusion
:: Blo … ; Industrial production
: Extrusion
:: Blow molding
:: Applied coatings
: Protective Coatings
: 3D printing
; Consumer products
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:: Whitewalls
: Cookware and bakeware
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:: Food container
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rdfs:comment |
Self-healing hydrogels are a specialized t … Self-healing hydrogels are a specialized type of polymer hydrogel. A hydrogel is a macromolecular polymer gel constructed of a network of crosslinked polymer chains. Hydrogels are synthesized from hydrophilic monomers by either chain or step growth, along with a functional crosslinker to promote network formation. A net-like structure along with void imperfections enhance the hydrogel's ability to absorb large amounts of water via hydrogen bonding. As a result, hydrogels, self-healing alike, develop characteristic firm yet elastic mechanical properties. Self-healing refers to the spontaneous formation of new bonds when old bonds are broken within a material. The structure of the hydrogel along with electrostatic attraction forces drive new bond formation through reconstructive covalent danmation through reconstructive covalent dan
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rdfs:label |
Self-healing hydrogels
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