| http://dbpedia.org/ontology/abstract
|
Disiamylborane (bis(1,2-dimethylpropyl)bor … Disiamylborane (bis(1,2-dimethylpropyl)borane, Sia2BH) is an organoborane used in organic synthesis. It is used for hydroboration–oxidation reactions of terminal alkynes, giving aldehydes via anti-Markovnikov hydration followed by tautomerization. Disiamylborane is relatively selective for terminal alkynes and alkenes vs internal alkynes and alkenes. Disiamylborane is prepared by hydroboration of trimethylethylene with diborane. The reaction stops at the secondary borane due to steric hindrance. secondary borane due to steric hindrance.
, Disiamylboran (systematický název (bis(1,2 … Disiamylboran (systematický název (bis(1,2-dimethylpropyl)boran, zkrácený vzorec Sia2BH) je organoboran používaný v organické syntéze k hydroboracím-oxidacím koncových alkynů za vzniku aldehydů proti Markovnikovovu pravidlu hydratací a následnou tautomerizací. Disiamylboran vykazuje větší selektivitu u koncových alkenů a alkynů než u těch vnitřních. Disiamylboran se připravuje hydroborací 2-methylbut-2-enu pomocí diboranu. Reakce se v důsledku sterického napětí zastaví u sekundárního boranu.kého napětí zastaví u sekundárního boranu.
, Bis(1,2-dimethylpropyl)boraan, meestal disiamylboraan genoemd, is een organische verbinding van boor, met als brutoformule C10H23B.
, Дисиамилборан — бороорганическое соединение с формулой B(C5H11)2H. Дисиамилборан обладает способностью гидроборировать алкены и алкины, на чём и основано его применение в органическом синтезе.
|
| http://dbpedia.org/ontology/iupacName
|
Bis(1,2-dimethylpropyl)borane
|
| http://dbpedia.org/ontology/thumbnail
|
http://commons.wikimedia.org/wiki/Special:FilePath/Disiamylborane.png?width=300 +
|
| http://dbpedia.org/ontology/wikiPageID
|
17504215
|
| http://dbpedia.org/ontology/wikiPageLength
|
2256
|
| http://dbpedia.org/ontology/wikiPageRevisionID
|
1041447419
|
| http://dbpedia.org/ontology/wikiPageWikiLink
|
http://dbpedia.org/resource/9-Borabicyclo%283.3.1%29nonane +
, http://dbpedia.org/resource/Organic_synthesis +
, http://dbpedia.org/resource/Hydroboration%E2%80%93oxidation_reaction +
, http://dbpedia.org/resource/Tetramethylethylene +
, http://dbpedia.org/resource/Diborane +
, http://dbpedia.org/resource/Organoborane +
, http://dbpedia.org/resource/Aldehyde +
, http://dbpedia.org/resource/Markovnikov%27s_rule +
, http://dbpedia.org/resource/Category:Alkylboranes +
, http://dbpedia.org/resource/Trimethylethylene +
, http://dbpedia.org/resource/Thexylborane +
, http://dbpedia.org/resource/Tautomer +
, http://dbpedia.org/resource/Hydroboration +
, http://dbpedia.org/resource/Alkyne +
, http://dbpedia.org/resource/Category:Reagents_for_organic_chemistry +
|
| http://dbpedia.org/property/imagealt
|
Ball-and-stick model of the disiamylborane molecule
, Skeletal formula of disiamylborane
|
| http://dbpedia.org/property/imagefile
|
Disiamylborane.png
, Disiamylborane-3D-balls.png
|
| http://dbpedia.org/property/imagesize
|
200
|
| http://dbpedia.org/property/iupacname
|
Bisborane
|
| http://dbpedia.org/property/verifiedfields
|
changed
|
| http://dbpedia.org/property/verifiedrevid
|
399911516
|
| http://dbpedia.org/property/watchedfields
|
changed
|
| http://dbpedia.org/property/wikiPageUsesTemplate
|
http://dbpedia.org/resource/Template:Stdinchicite +
, http://dbpedia.org/resource/Template:Fdacite +
, http://dbpedia.org/resource/Template:Chembox_Properties +
, http://dbpedia.org/resource/Template:Chembox +
, http://dbpedia.org/resource/Template:Chembox_Identifiers +
, http://dbpedia.org/resource/Template:Cascite +
, http://dbpedia.org/resource/Template:Chemspidercite +
|
| http://purl.org/dc/terms/subject
|
http://dbpedia.org/resource/Category:Alkylboranes +
, http://dbpedia.org/resource/Category:Reagents_for_organic_chemistry +
|
| http://purl.org/linguistics/gold/hypernym
|
http://dbpedia.org/resource/Organoborane +
|
| http://www.w3.org/ns/prov#wasDerivedFrom
|
http://en.wikipedia.org/wiki/Disiamylborane?oldid=1041447419&ns=0 +
|
| http://xmlns.com/foaf/0.1/depiction
|
http://commons.wikimedia.org/wiki/Special:FilePath/Disiamylborane-3D-balls.png +
, http://commons.wikimedia.org/wiki/Special:FilePath/Disiamylborane.png +
|
| http://xmlns.com/foaf/0.1/isPrimaryTopicOf
|
http://en.wikipedia.org/wiki/Disiamylborane +
|
| owl:sameAs |
http://ru.dbpedia.org/resource/%D0%94%D0%B8%D1%81%D0%B8%D0%B0%D0%BC%D0%B8%D0%BB%D0%B1%D0%BE%D1%80%D0%B0%D0%BD +
, https://global.dbpedia.org/id/2GEyA +
, http://yago-knowledge.org/resource/Disiamylborane +
, http://sr.dbpedia.org/resource/Disiamilboran +
, http://cs.dbpedia.org/resource/Disiamylboran +
, http://nl.dbpedia.org/resource/Bis%281%2C2-dimethylpropyl%29boraan +
, http://rdf.freebase.com/ns/m.04g0w7f +
, http://fi.dbpedia.org/resource/Disiamyyliboraani +
, http://azb.dbpedia.org/resource/%D8%AF%DB%8C%E2%80%8C%D8%B3%DB%8C%D8%A7%D9%85%DB%8C%D9%84%E2%80%8C%D8%A8%D9%88%D8%B1%D8%A7%D9%86 +
, http://dbpedia.org/resource/Disiamylborane +
, http://sh.dbpedia.org/resource/Disiamilboran +
, http://www.wikidata.org/entity/Q2402883 +
, http://fa.dbpedia.org/resource/%D8%AF%DB%8C%E2%80%8C%D8%B3%DB%8C%D8%A7%D9%85%DB%8C%D9%84%E2%80%8C%D8%A8%D9%88%D8%B1%D8%A7%D9%86 +
|
| rdf:type |
http://umbel.org/umbel/rc/ChemicalSubstanceType +
, http://dbpedia.org/class/yago/Idea105833840 +
, http://dbpedia.org/class/yago/Content105809192 +
, http://dbpedia.org/class/yago/WikicatOrganoboronCompounds +
, http://dbpedia.org/ontology/ChemicalSubstance +
, http://www.ontologydesignpatterns.org/ont/dul/DUL.owl#ChemicalObject +
, http://dbpedia.org/class/yago/Abstraction100002137 +
, http://dbpedia.org/class/yago/Concept105835747 +
, http://www.wikidata.org/entity/Q11173 +
, http://dbpedia.org/class/yago/Compound105870180 +
, http://dbpedia.org/class/yago/PsychologicalFeature100023100 +
, http://dbpedia.org/ontology/ChemicalCompound +
, http://dbpedia.org/class/yago/Whole105869584 +
, http://dbpedia.org/class/yago/Cognition100023271 +
|
| rdfs:comment |
Дисиамилборан — бороорганическое соединение с формулой B(C5H11)2H. Дисиамилборан обладает способностью гидроборировать алкены и алкины, на чём и основано его применение в органическом синтезе.
, Bis(1,2-dimethylpropyl)boraan, meestal disiamylboraan genoemd, is een organische verbinding van boor, met als brutoformule C10H23B.
, Disiamylboran (systematický název (bis(1,2 … Disiamylboran (systematický název (bis(1,2-dimethylpropyl)boran, zkrácený vzorec Sia2BH) je organoboran používaný v organické syntéze k hydroboracím-oxidacím koncových alkynů za vzniku aldehydů proti Markovnikovovu pravidlu hydratací a následnou tautomerizací. Disiamylboran vykazuje větší selektivitu u koncových alkenů a alkynů než u těch vnitřních. Disiamylboran se připravuje hydroborací 2-methylbut-2-enu pomocí diboranu. Reakce se v důsledku sterického napětí zastaví u sekundárního boranu.kého napětí zastaví u sekundárního boranu.
, Disiamylborane (bis(1,2-dimethylpropyl)bor … Disiamylborane (bis(1,2-dimethylpropyl)borane, Sia2BH) is an organoborane used in organic synthesis. It is used for hydroboration–oxidation reactions of terminal alkynes, giving aldehydes via anti-Markovnikov hydration followed by tautomerization. Disiamylborane is relatively selective for terminal alkynes and alkenes vs internal alkynes and alkenes. Disiamylborane is prepared by hydroboration of trimethylethylene with diborane. The reaction stops at the secondary borane due to steric hindrance. secondary borane due to steric hindrance.
|
| rdfs:label |
Disiamylborane
, Disiamylboran
, Bis(1,2-dimethylpropyl)boraan
, Дисиамилборан
|
